Natalia B. Shustova
|Title:||Assistant Professor / Inorganic
Catalysis / Crystallography / Materials / Organic / Physical and Theoretical / Solid State / Supramolecular
|Department of Chemistry and Biochemistry|
Office: GSRC 533
Lab: GSRC 405, 803-777-9852
Lab 2: GSRC 511, 803-777-4241
B.S., 2002, Moscow State University
M.S., 2004, Moscow State University
Ph.D., 2005, Physical Chemistry, Moscow State University
Ph.D., 2010, Inorganic Chemistry, Colorado State University
Honors and Awards
Breakthrough Award, 2017; Alfred P. Sloan Research Award, 2017; Cottrell Scholar Award, 2017; Scialog Fellow, Research Corporation for Science Advancement, 2017; National Science Foundation Career Award, 2016.
Research in my group will focus on materials for sustainable energy conversion, sensing, switches, and artificial biomimetic systems. Development of these materials will involve the synthesis and characterization of the porous (e.g., metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs)) and graphitic materials. Specifically, three main directions related to 1) morphology control of the active layer of a bulk heterojunction solar cell, 2) light harvesting and energy transfer in well-defined self-assemblies, and 3) design of artificial scaffolds mimicking protein behavior will be developed.
Students who are interested in inorganic chemistry, materials, or physical chemistry are strongly encouraged to join. Each student in my group will be trained in synthesis and techniques for manipulating air-sensitive compounds, powder diffraction analysis, single-crystal X-ray crystallography, thermogravimetric analysis, and spectroscopy (UV-vis, IR, Fluorescence).
The Active Layer Morphology Control in Organic Photovoltaics. Increase of efficiency in the currently used bulk heterojunction solar cells, the realistic candidates for an efficient photoenergy conversion, can be achieved through the precise control of the active layer morphology at the nanoscale level. The ultimate goal of the research in my group is to design new materials that can be used as active layer components, which will lead to efficiency enhancement of solar cells.
Light Harvesting and Controllable Energy Transfer in Well-Defined Self-Assemblies. Light harvesting chromophore assemblies with an ability to control Förster resonance energy transfer (FRET) processes are required for the preparation of the next generation organic photovoltaics, molecular-scale digital switches, and sensors coupled to FRET. To address these issues, a new strategy to control energy transfer processes in self-assembled well-defined arrays of chromophores will be developed.
Dolgopolova, E. A., Brandt, A. J.; Ejegbavwo, O. A.; Duke, A. S.; Maddumapatabandi, T. D.; Galhenage, R. P.; Larson, B. W.; Reid, O. G.; Ammal, S. C.; Heyden, A.; Chandrashekhar, Mvs; Stavila, V.; Chen, D. A.; Shustova, N. B.* “Electronic Properties of Bimetallic Metal-Organic Frameworks (MOFs): Tailoring the Density of Electronic States through MOF Modularity” J. Am. Chem. Soc., 2017, 139, 5201-5209. DOI: 10.1021/jacs.7b01125.
Rice, A. M.; Fellows; W. B.; Dolgopolova, E. A.; Greytak, A. B.; Vannucci, A. K.; Smith, M. D.; Karakalos, S. G.; Krause, J. A.; Avdoshenko, S. M.; Popov, A. A.; Shustova, N. B.* “Hierarchical Corannulene-Based Materials: Energy Transfer and Solid-State Photophysics” Angew. Chem. Int. Ed. 2017, 129, 4596–4600.
Fellows, B. W.; Rice, A. M; Williams, D. E.; Dolgopolova, E. A.; Vannucci, A. K.;
Pellechia, P.J.; Smith, M. D.; Krause, J. A.; Shustova, N. B.* "Redox-Active Corannulene Buckybowls in a Crystalline Hybrid Scaffold" Angew. Chem. Int. Ed. 2016, 55, 2195–2199. (highlighted on the cover).
Williams, D. E.; Godfrey, D. C.; Ermolaeva, E. D. Pellechia, P. J.; Greytak, A. B.;
Smith, M. D.; Avdoshenko, S. M; Popov, A. A.; Shustova, N. B.* “Fulleretic Well-Defined Scaffolds: Donor-Fullerene Alignment Through Metal Coordination
and Its Effect on Photophysics” Angew. Chem. Int. Ed. 2016, 55, 9070–9074.
Williams, D. E.; Dolgopolova, E. A.; Pellechia, P.J.; Palukoshka, A.; Wilson, T. J.; Tan, R.; Maier, J. M.; Tan, R.; Greytak, A. B.; Smith, M. D.; Krause, J. A.; Shustova, N. B.* A Mimic of the Green Fluorescent Protein β-barrel: Photophysics and Dynamics of Confined Chromophores Defined by a Rigid Porous Scaffold. J. Am. Chem. Soc. 2015, 137, 2223–2226. DOI: 10.1021/ja5131269.